基于整体柱的表面增强拉曼光谱法检测非法染色青黛

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基于整体柱的表面增强拉曼光谱法检测非法染色青黛

郑滨兴, 吕迪亚, 方芳, 刘艳华, 李丹, 陆峰, 许激扬

文章导航 > 药学实践与服务 > 2015 > 33(5): 426-428,459

郑滨兴, 吕迪亚, 方芳, 刘艳华, 李丹, 陆峰, 许激扬. 基于整体柱的表面增强拉曼光谱法检测非法染色青黛[J]. 药学实践与服务, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

引用本文:

郑滨兴, 吕迪亚, 方芳, 刘艳华, 李丹, 陆峰, 许激扬. 基于整体柱的表面增强拉曼光谱法检测非法染色青黛[J]. 药学实践与服务, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

ZHENG Binxing, LV Diya, FANG Fang, LIU Yanhua, LI Dan, LU Feng, XU Jiyang. Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column[J]. Journal of Pharmaceutical Practice and Service, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

Citation:

ZHENG Binxing, LV Diya, FANG Fang, LIU Yanhua, LI Dan, LU Feng, XU Jiyang. Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column[J]. Journal of Pharmaceutical Practice and Service, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

基于整体柱的表面增强拉曼光谱法检测非法染色青黛

doi: 10.3969/j.issn.1006-0111.2015.05.011

1.
中国药科大学生命科学与技术学院, 江苏南京 210009
2.
第二军医大学药学院, 上海 200433
3.
福建中医药大学药学院, 福建福州 350108

Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column

1.
School of Life Science and Technology, China Pharmaceutical University, Nanjing 210009, China
2.
School of Pharmacy, the Second Military Medical University, Shanghai 200433, China
3.
School of Pharmacy, Fujian University of Traditional Chinese Medicine, Fuzhou 350108, China

摘要: 目的建立基于整体柱的表面增强拉曼光谱(surface enhanced Raman spectroscopy, SERS)法快速检测非法染色的青黛。方法采用混合溶剂乙醇-水(1:1,V/V)对染色青黛中的染料进行提取,利用整体柱中网状孔隙有助于银纳米颗粒在空间上耦合的特性,将样品溶液和银胶溶液混匀后滴加于整体柱上进行SERS光谱采集。结果此法可得到青黛中染色掺伪量低至500 μg/kg的孔雀石绿SERS信号。结论该方法具有快速、简便、专属性强等优点,可运用于中药材青黛非法染色的快速检测。
- 表面增强拉曼光谱 /
- 整体柱 /
- 非法染色 /
- 青黛 /
- 孔雀石绿
Abstract: Objective To develop a rapid SERS detection method based on monolithic column for detection of dye adulterated natural indigo. Methods The dyes in natural indigo were extracted and mixed with silver colloid. The spectra were recorded after applying the mixture solution to the monolithic column since the intertwined pores in monolithic column could contribute for the distribution of silver nanoparticles. Results SERS signals of malachite green dyed natural indigo at quantity as low as 500 μg/kg could be obtained. Conclusion This simple,fast and specific SERS detection method based on monolithic column could be used for rapid detection of stained natural indigo.
- surface enhanced Raman spectroscopy (SERS) /
- monolithic column /
- adulteration /
- natural indigo /
- malachite green

[1]	吴云燕, 孙雪妮. 中药饮片染色现象不容忽视[J]. 中草药, 2001, 32(8): 752-753.
[2]	姚志昂. 青黛的质量考察与掺伪研究[D]. 成都: 成都中医药大学, 2011.
[3]	蒋玲, 饶伟文. 中药染色掺假的研究进展[J]. 首都医药, 2011, 18(16): 16-18.
[4]	谢云飞, 李言, 余慧, 等. 整体柱-金复合基底的制备及其在色素 SERS 检测的应用[J]. 光谱学与光谱分析, 2014, 34(3): 681-684.
[5]	Kubackova J, Fabriciova G, Miskovsky P, et al. Sensitive surface-enhanced Raman spectroscopy (SERS) detection of organochlorine pesticides by alkyl dithiol-functionalized metal nanoparticles-induced plasmonic hot spots[J]. Anal Chem, 2015, 87(1): 663-669.
[6]	渠陆陆, 李大伟, 翟文磊, 等. 基于表面增强拉曼光谱的水中芳香胺类污染物现场快速检测技术[J]. 环境化学, 2011, 30(8): 1486-1492.
[7]	樊玉霞, 赖克强, 黄轶群. 表面增强拉曼光谱技术在食品痕量化学危害检测中的应用[J]. 光谱学与光谱分析, 2014, 34(7): 1859-1864.
[8]	Li Q, Du Y, Tang H, et al. Ultra sensitive surface-enhanced Raman scattering detection based on monolithic column as a new type substrate[J]. J Raman Spectrosc, 2012, 43(10): 1392-1396.
[9]	Svec F, Fréchet JMJ. Continuous rods of macroporous polymer as high-performance liquid chromatography separation media[J]. Anal Chem, 1992, 64(7): 820-822.
[10]	Lee PC, Meisel D. Adsorption and surface-enhanced Raman of dyes on silver and gold sols[J]. J Phys Chem, 1982, 86(17): 3391-3395.
[11]	Zhu Q, Cao Y, Cao Y, et al. Rapid on-site TLC-SERS detection of four antidiabetes drugs used as adulterants in botanical dietary supplements[J]. Anal Bioanal Chem, 2014, 406(7): 1877-1884.

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基于整体柱的表面增强拉曼光谱法检测非法染色青黛

doi: 10.3969/j.issn.1006-0111.2015.05.011

1. 中国药科大学生命科学与技术学院, 江苏南京 210009

2. 第二军医大学药学院, 上海 200433

3. 福建中医药大学药学院, 福建福州 350108

收稿日期: 2015-02-09
修回日期: 2015-05-28

关键词:

表面增强拉曼光谱 /

摘要: 目的建立基于整体柱的表面增强拉曼光谱(surface enhanced Raman spectroscopy, SERS)法快速检测非法染色的青黛。方法采用混合溶剂乙醇-水(1:1,V/V)对染色青黛中的染料进行提取,利用整体柱中网状孔隙有助于银纳米颗粒在空间上耦合的特性,将样品溶液和银胶溶液混匀后滴加于整体柱上进行SERS光谱采集。结果此法可得到青黛中染色掺伪量低至500 μg/kg的孔雀石绿SERS信号。结论该方法具有快速、简便、专属性强等优点,可运用于中药材青黛非法染色的快速检测。

English Abstract

郑滨兴, 吕迪亚, 方芳, 刘艳华, 李丹, 陆峰, 许激扬. 基于整体柱的表面增强拉曼光谱法检测非法染色青黛[J]. 药学实践与服务, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

引用本文:

郑滨兴, 吕迪亚, 方芳, 刘艳华, 李丹, 陆峰, 许激扬. 基于整体柱的表面增强拉曼光谱法检测非法染色青黛[J]. 药学实践与服务, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

ZHENG Binxing, LV Diya, FANG Fang, LIU Yanhua, LI Dan, LU Feng, XU Jiyang. Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column[J]. Journal of Pharmaceutical Practice and Service, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

Citation:

ZHENG Binxing, LV Diya, FANG Fang, LIU Yanhua, LI Dan, LU Feng, XU Jiyang. Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column[J]. Journal of Pharmaceutical Practice and Service, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011

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